 
          3232
        
        
          Proceedings of the 18
        
        
          th
        
        
          International Conference on Soil Mechanics and Geotechnical Engineering, Paris 2013
        
        
          Figure 1 shows part of their results. Seawater and fresh water
        
        
          were tested with Portland cement and powdered blast furnace
        
        
          slag (PBFS) as additives. When fresh water was used, cement
        
        
          was more effective than PBFS in solidifying GBFS. But when
        
        
          seawater was used, PBFS was more effective than cement.
        
        
          Using seawater and PBFS was the most effective combination.
        
        
          3
        
        
          ISSUES REGARDING APPLYING THE GBFS
        
        
          SOLIDIFICATION ACCELERATION METHOD IN THE
        
        
          FIELD
        
        
          There are several issues to consider when determining the most
        
        
          appropriate mixture of GBFS and PBFS for accelerating GBFS
        
        
          solidification: (1) the material can separate during construction,
        
        
          (2) it may separate after construction because of water flow (3)
        
        
          separation of the mixture is likely to affect how the GBFS
        
        
          solidifies, (4) the flow of pore water can affect solidification,
        
        
          and (5) GBFS may solidify differently when the pore water
        
        
          changes from sea water to fresh water (Kikuchi et al. 2010).
        
        
          In the present study, we examine issues (1) to (5). First, we
        
        
          present experimental results regarding issues (2), (3), and (4).
        
        
          We then explain a way to prevent issue (1), and finally consider
        
        
          issue (5).
        
        
          3.1
        
        
          
            Possibility of material separation after construction
          
        
        
          The physical properties of the GBFS used were
        
        
          
        
        
          s
        
        
          = 2.845
        
        
          g/cm
        
        
          3
        
        
          ,
        
        
          
        
        
          dmin
        
        
          = 1.175 g/cm
        
        
          3
        
        
          ,
        
        
          
        
        
          dmax
        
        
          = 1.508 g/cm
        
        
          3
        
        
          , D
        
        
          15
        
        
          = 0.28 mm,
        
        
          and D
        
        
          50
        
        
          = 0.38 mm. The physical properties of the PBFS used
        
        
          were
        
        
          
        
        
          s
        
        
          = 2.890 g/cm
        
        
          3
        
        
          , with 5000 to 7000 cm
        
        
          2
        
        
          /g of specific
        
        
          surface area. Artificial seawater was used as pore water.
        
        
          The diameter of the PBFS was about 4
        
        
          
        
        
          m assuming
        
        
          spherical particles with no small holes. Thus, the GBFS and
        
        
          PBFS may separate when the mixture is poured onto the seabed.
        
        
          The ratio of D
        
        
          15
        
        
          for GBFS to D
        
        
          85
        
        
          for PBFS is more than 50.
        
        
          This ratio is an indicator of the possibility of material separation
        
        
          due to water flow through the material (Ishihara 2001).
        
        
          We conducted experiments on the separation of the PBFS
        
        
          from the mixture. In this series of experiments, specimens with
        
        
          two layers were prepared. The lower layer of the specimen was
        
        
          a mixture of GBFS with 20% PBFS by weight. The upper layer
        
        
          was only GBFS. The relative density of each layer was 50%.
        
        
          Water flowed from the bottom of the specimen with a
        
        
          hydraulic gradient of from 10 to 40. This test was conducted in
        
        
          a triaxial apparatus at a confining pressure of 50 kN/m
        
        
          2
        
        
          to
        
        
          prevent boiling. The outlet velocity of the water at a hydraulic
        
        
          gradient of 40 was 120 m/day. The total outlet water volume
        
        
          from the specimen was 6 times the void volume of the specimen.
        
        
          Figure 2 shows close-up X-ray CT images of the boundary
        
        
          between the layers of the specimen, where the contrast reflects
        
        
          the density of the material. Comparing the images before and
        
        
          after water flow, small differences can be observed. This means
        
        
          that although there may be a little separation when the peak
        
        
          velocity of the water flow is 120 m/day, complete separation of
        
        
          the material does not occur under these conditions.
        
        
          In practice, the water flow velocity in GBFS used as backfill
        
        
          for gravity quay walls is around several m/day. Thus, GBFS and
        
        
          PBFS will never separate after construction.
        
        
          Before water flow                After water flow of 120m/day
        
        
          Figure 2. Close-up X-ray CT images at mid-height of the specimen.
        
        
          3.2
        
        
          
            Solidification of GBFS after material separation
          
        
        
          The effect of material separation on the solidification
        
        
          characteristics of the material is examined in this section.
        
        
          The GBFS and PBFS used here were the same as those used
        
        
          in section 3.1. The relative densities of the specimens were 50%.
        
        
          The pore water used was artificial sea water. In each specimen,
        
        
          7.5% PBFS by weight was added to the GBFS. We tested four
        
        
          experimental mixing regimes: (1) GBFS and PBFS were mixed
        
        
          homogeneously (HMT), (2) PBFS was mixed with GBFS, then
        
        
          artificial sea water was added to achieve a 10% water content
        
        
          ratio and the mixture was cured in air for a week (prior
        
        
          homogeneous mixing treatment or PHMT), (3) One PBFS layer
        
        
          was sandwiched between two layers of GBFS, and (4) Two
        
        
          PBFS layers were sandwiched between three GBFS layers.
        
        
          Each specimen was saturated with artificial sea water and
        
        
          sealed, then cured for a designated period at a constant
        
        
          temperature of 20 degrees centigrade. Each specimen’s
        
        
          unconfined compression strength was measured after the
        
        
          designated curing period.
        
        
          Figure 3 shows the relationship between the curing duration
        
        
          and unconfined strength. The unconfined compression strengths
        
        
          using HMT and PHMT exceeded 200 kN/m
        
        
          2
        
        
          after 14 days of
        
        
          curing. These strengths increased as the curing time lengthened.
        
        
          When the materials were separated, such as in cases (3) and (4),
        
        
          the unconfined compression strengths were very low. Figure 4
        
        
          shows examples of the failure states for each case.
        
        
          0
        
        
          500
        
        
          1000
        
        
          1500
        
        
          2000
        
        
          2500
        
        
          3000
        
        
          3500
        
        
          0
        
        
          30
        
        
          60
        
        
          Unconfined compression strength
        
        
          q
        
        
          u
        
        
          (kN/m
        
        
          2
        
        
          )
        
        
          Curing time  (days)
        
        
          90
        
        
          HMT
        
        
          PHMT
        
        
          One layer
        
        
          Two layers
        
        
          Figure 3. Change of unconfined compression strength with curing time.
        
        
          (a) HMT          (b) PHMT           (c) One layer       (d) Two layers
        
        
          Figure 4. Failure modes of specimens in each mixing regime
        
        
          These results show the importance of thoroughly mixing the
        
        
          GBFS and PBFS in accelerating the solidification of the GBFS.
        
        
          3.3
        
        
          
            Solidification of GBFS underground with flowing water
          
        
        
          In previous research, movement of pore water has been shown
        
        
          to prevent GBFS solidification (Kitayama 2003). In this section,
        
        
          we examine how pore water flow effects GBFS solidification.
        
        
          In this series of experiments, two water flow conditions and two
        
        
          mixing conditions were tested.
        
        
          We used the same GBFS and PBFS as in section 3.1, and the
        
        
          HMT (1) and PHMT (2) mixing regimes from section 3.2.