 
          3233
        
        
          Technical Committee 307 /
        
        
          
            Comité technique 307
          
        
        
          In this series, sand boxes 30 cm wide, 30 cm long, and 50 cm
        
        
          high were fitted with a bulb for supplying water, located 3 cm
        
        
          from the bottom. Model ground 30 cm high was constructed of
        
        
          a mixture of GBFS and PBFS with 50% relative density. This
        
        
          was saturated with artificial sea water at the beginning of the
        
        
          test. Tests were run under static water and flowing water
        
        
          conditions. In the static water case, the pore water was never
        
        
          changed during the experiment. In the flowing water case, a
        
        
          volume of water equal to the volume of the voids in the ground
        
        
          was supplied slowly from the bottom of the ground once every
        
        
          three days. Curing continued for two months at a constant
        
        
          temperature of 20 degrees centigrade. After curing, the bearing
        
        
          strength distribution of the ground was measured using a soil
        
        
          hardness meter, and was converted to unconfined compression
        
        
          strengths.
        
        
          The results show that the HMT-treated material subjected to
        
        
          static water conditions was the strongest. The material that had
        
        
          undergone HMT was weaker when cured in flowing water.
        
        
          However, for the PHMT-treated material, the opposite was true.
        
        
          With flowing water the PHMT material was stronger than the
        
        
          HMT material, meaning that PHMT has a higher potential to
        
        
          solidify GBFS than HMT under non-static water conditions.
        
        
          3.4
        
        
          
            Improving resistance to separation during construction
          
        
        
          
            using PHMT
          
        
        
          For this series of experiments, we used GBFS with the
        
        
          following physical properties:
        
        
          
        
        
          s
        
        
          = 2.808 g/cm
        
        
          3
        
        
          ,
        
        
          
        
        
          dmin
        
        
          = 1.199
        
        
          g/cm
        
        
          3
        
        
          , and
        
        
          
        
        
          dmax
        
        
          = 1.562 g/cm
        
        
          3
        
        
          . The median particle diameter
        
        
          (D
        
        
          50
        
        
          ) was 0.74 mm. The physical properties of the PBFS were
        
        
          
        
        
          s
        
        
          = 2.890 g/cm
        
        
          3
        
        
          , with 5000 to 7000 cm
        
        
          2
        
        
          /g of specific surface
        
        
          area. Artificial seawater was used as pore water.
        
        
          As the GBFS and PBFS may separate when the mixture is
        
        
          poured onto the seabed, PHMT was used to counter this
        
        
          problem. With PHMT, some of the PBFS attaches to the GBFS
        
        
          granules, making the mixture more resistant to separation and
        
        
          decreasing the turbidity the mixture causes in water.
        
        
          We mixed 10% seawater and 7.5% by weight of PBFS with
        
        
          GBFS and cured the mixture for a designated period in air. We
        
        
          measured the turbidity it caused after 0, 3, 7, 10, and 14 days of
        
        
          curing. In each test, about 0.460 N of the PHMT mixture was
        
        
          poured into 1000 ml of pure water and stirred well, then left to
        
        
          sit for 30 min. A turbidity meter was used for measurements.
        
        
          0
        
        
          500
        
        
          1000
        
        
          1500
        
        
          2000
        
        
          2500
        
        
          0 2 4 6 8 10 12 14
        
        
          Suspended PBFS
        
        
          concentration(mg/ℓ)
        
        
          Curing time (days)
        
        
          Just after mixing
        
        
          30 min after mixing
        
        
          Figure 5. Change in suspended PBFS concentration with curing time.
        
        
          Figure 5 shows how the suspended material concentration
        
        
          changed with curing time. The level just after mixing decreased
        
        
          to one-fourth of its initial value after 7 days of curing. The
        
        
          concentration 30 min after mixing became negligible after 7
        
        
          days of curing.
        
        
          A mixture of GBFS and PHMT is thus shown to be effective
        
        
          in reducing the amount of material separation during
        
        
          construction.
        
        
          3.5
        
        
          
            Effects of changing from sea water to fresh water on the
          
        
        
          
            solidification of PHMT-treated GBFS
          
        
        
          Here, we address issue (5) described above. The follow-up
        
        
          survey about GBFS used as backfill noted in the introduction
        
        
          revealed that the pore water in the GBFS layer changed
        
        
          completely from seawater to fresh water over a period of 4
        
        
          months (Kikuchi et al. 2005). This phenomenon occurs because
        
        
          the mean ground water level is higher than the mean sea level
        
        
          and rainfall supplies fresh water. Figure 1 shows that GBFS
        
        
          mixed with PBFS in seawater solidified in a month. With this in
        
        
          mind, we checked the effect of a pore water transition in a series
        
        
          of laboratory experiments.
        
        
          Figure 6 shows how the experiment was set up. The box
        
        
          holding the sand was 800 mm long, 500 mm high, and 500 mm
        
        
          wide. We used PHMT cured for 7 days, made following the
        
        
          procedure described in section 3.2. The PHMT layer was made
        
        
          when wet and was covered by the sand layer. We used silica
        
        
          sand #4 (
        
        
          
        
        
          s
        
        
          = 2.644 g/cm
        
        
          3
        
        
          ,
        
        
          
        
        
          dmin
        
        
          = 1.342 g/cm
        
        
          3
        
        
          , and
        
        
          
        
        
          dmax
        
        
          = 1.618
        
        
          g/cm
        
        
          3
        
        
          ). The relative densities of the PHMT and sand were 50%.
        
        
          The water used to make the layers was artificial seawater,
        
        
          except for case 4 (Table 2.), in which fresh water was used. The
        
        
          shape of each layer is shown in Fig. 6. After making the model
        
        
          ground, 6 standpipes were installed at the positions marked No.
        
        
          1, No. 2, and No. 3 to collect pore water. Two pipes were
        
        
          installed at each location to collect water from different depths.
        
        
          The open circles in Fig. 6 show the points where pore water was
        
        
          collected. Water was supplied as shown in the upper right part
        
        
          of the figure at a rate of 6
        
        
          
            l
          
        
        
          per day. Effluent flowed from the
        
        
          bottom of the apparatus as shown in the figure. Since the void
        
        
          space in the model ground layer was about 84
        
        
          
            l
          
        
        
          , the hydraulic
        
        
          retention time of the water in the apparatus was 14 days. Each
        
        
          experiment was conducted at 20 degrees centigrade. As the
        
        
          room was not perfectly temperature-controlled, its temperature
        
        
          was somewhat affected by the outside temperature.
        
        
          Influent
        
        
          500
        
        
          320
        
        
          Effluent
        
        
          800
        
        
          480
        
        
          150 170 180
        
        
          300
        
        
          100
        
        
          200
        
        
          200
        
        
          100
        
        
          100
        
        
          250
        
        
          300
        
        
          100
        
        
          100
        
        
          Effluent
        
        
          490
        
        
          Silica sand
        
        
          #4
        
        
          No.1 No.2 No.3
        
        
          :Measuring point
        
        
          100
        
        
          50
        
        
          (Depth: 500)
        
        
          Unit: mm
        
        
          Impermeable liner
        
        
          GBFS(PHMT)
        
        
          Figure 6. Experimental setup
        
        
          During the experiment, pore water was collected from each
        
        
          point at designated times, and pH and salinity were measured.
        
        
          After 8 weeks, the strength of the PHMT-treated GBFS was
        
        
          measured with a Yamanaka soil hardness meter (Kikuchi et al.
        
        
          2010). About 2000 strength measurements were made in each
        
        
          case. The data collected were converted to unconfined
        
        
          compression strengths using a relationship between strength and
        
        
          hardness determined before the experiment.
        
        
          Table 1 shows the types of water supplied in each case.
        
        
          Table 1. Experiment conditions
        
        
          Case
        
        
          Condition
        
        
          Case 1
        
        
          Sea water supplied for 8 weeks
        
        
          Case 2
        
        
          Sea water supplied for 6 weeks, then pure water
        
        
          supplied for 2 weeks