 
          1186
        
        
          Proceedings of the 18
        
        
          th
        
        
          International Conference on Soil Mechanics and Geotechnical Engineering, Paris 2013
        
        
          15, and 20 percent, respectively.  Data and diffractograms for
        
        
          the mixed-layer clay determinations are shown in Birchmier
        
        
          (2005).  These values fall within the data compiled by Schultz
        
        
          (1978) for mixed-layer clay minerals in Pierre Shale.  Overlays
        
        
          of diffractograms of bulk samples for the wet/dry cycles of the
        
        
          70.3 meter depth showed little change over the weathering
        
        
          cycles except for the reduction of gypsum particle size during
        
        
          the initial cycles.  The combination of the decrease in the
        
        
          gypsum peak intensity at 7.63 Å, and the constant 4.28 Å and
        
        
          3.8 Å peak intensities during cycling suggests the breakdown of
        
        
          the gypsum particles.
        
        
          4 DISCUSSION
        
        
          Residual friction angles for the wet/dry cycles decreased from
        
        
          6.8° to 5.4°, 6.1° to 5.2°, and 6.7° to 5.4° for the depths 63.0,
        
        
          63.6, and 70.3 m, respectively.  A one degree drop in a material
        
        
          with an initial residual friction angle of 6.5° is significant.  For a
        
        
          given normal stress and negligible residual cohesion, the factor
        
        
          of safety would be reduced by a ratio of 1.2.  Exposure and
        
        
          removal of confining stresses during construction activities in
        
        
          Pierre Shale could cause wetting and drying to occur and lead to
        
        
          slope failures.
        
        
          The residual friction angle for each cycle for the three depths
        
        
          was determined from ring-shear tests.  The residual friction
        
        
          angle dropped almost 1.5 degrees for the 63.0 meter depth,
        
        
          nearly one degree for the 63.6 meter sample, and 1.3 degrees for
        
        
          the 70.3 meter depth during the wet/dry cycles.  An unexpected
        
        
          increase in strength was observed in the later stages of the 70.3
        
        
          meter cycles.  Similarities in the 63.6 and 70.3 meter residual
        
        
          friction angle plots are apparent for the first two cycles.
        
        
          Residual friction angles for the wet/dry cycles decreased from
        
        
          6.8° to 5.4°, 6.1° to 5.2°, and 6.7° to 5.4° for the depths tested.
        
        
          A degree drop in a material with an initial residual friction angle
        
        
          of 6.5° is significant.  For a given normal stress and negligible
        
        
          residual cohesion, the factor of safety would be reduced by a
        
        
          ratio of 1.2.  Exposure and removal of confining stresses during
        
        
          construction activities in Pierre Shale could cause wetting and
        
        
          drying to occur and lead to slope failures.
        
        
          5 CONCLUSIONS
        
        
          Minor mineralogical changes were observed in the wet/dry
        
        
          cycles similar to the weathering occurrences in Pierre Shale.
        
        
          Gypsum concentrations decreased initially in the wet/dry cycles.
        
        
          The low residual friction angles of 6.1° to 6.8° decreased an
        
        
          additional 0.8° to 1.4° during the wet/dry cycles.  A significant
        
        
          fabric contrast was apparent after three cycles as the material’s
        
        
          structure became more massive.  The most noticeable difference
        
        
          in the cycles was the particle settlement rates.  Excessive
        
        
          cycling caused particles to stay up in suspension for weeks to
        
        
          months longer than the un-cycled material.  This observation
        
        
          indicates clay aggregates are becoming smaller and going
        
        
          towards their unit-cell size.  The reduction in size increased the
        
        
          clay fraction, contributing to the residual strength decrease.
        
        
          The mechanical behavior varied for the samples analyzed.
        
        
          The material with larger amounts of illite in the mixed-layer
        
        
          clay mineral showed a decrease in residual strength following
        
        
          Stark and Eid's (1994) curves.  The material with higher
        
        
          amounts of montmorillonite in the mixed-layer clay mineral
        
        
          showed little change in the liquid limits, a contrast to the other
        
        
          sample.  A decrease in residual strength was observed for the
        
        
          first two cycles but increased thereafter.  The contrasting
        
        
          behavior shows the heterogeneity of the material and the
        
        
          difficulties in determining design parameters.  The
        
        
          mineralogical changes and the disintegration of aggregates
        
        
          during wetting and drying are concluded to be more influential
        
        
          than physico-chemical effects.
        
        
          6 ACKNOWLEDGEMENTS
        
        
          The authors thank the engineers of the U.S. Army Corps of
        
        
          Engineers Project Office in Pierre, SD for their help in
        
        
          obtaining the samples of Pierre Shale. Ashley Schwaller,
        
        
          undergraduate student at Iowa State University, is thanked for
        
        
          conducting the XRD tests.  This material is based on work
        
        
          supported by the National Science Foundation under Grant Nos.
        
        
          CMS-0201482 and CMS-0227874.  This support is gratefully
        
        
          acknowledged.  Any opinions, findings and conclusions or
        
        
          recommendations expressed in this material are those of the
        
        
          authors and do not necessarily reflect the views of the National
        
        
          Science Foundation.
        
        
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