 
          1017
        
        
          Technical Committee 105 /
        
        
          
            Comité technique 105
          
        
        
          where
        
        
          p
        
        
          a
        
        
          is standard atmospheric pressure (i.e., 0.1 MPa);
        
        
          
        
        
          w
        
        
          is
        
        
          the water density at 4C;
        
        
          T
        
        
          0
        
        
          is the reference temperture (1C is
        
        
          used herein).
        
        
          The tangential contact stiffness
        
        
          K
        
        
          s
        
        
          then relates to
        
        
          K
        
        
          n
        
        
          based on
        
        
          PFC2D Guidelines (Itasca, 2004) by
        
        
          K
        
        
          s
        
        
          = 2/3
        
        
          K
        
        
          n
        
        
          .
        
        
          0.72
        
        
          0.76
        
        
          0.80
        
        
          0.84
        
        
          1.8
        
        
          2.1
        
        
          2.4
        
        
          2.7
        
        
          1.5MPa
        
        
          4MPa
        
        
          Elastic modulus
        
        
          (
        
        
          10
        
        
          8
        
        
          Pa
        
        
          )
        
        
          Density
        
        
          
        
        
          g/cm
        
        
          3
        
        
          
        
        
          p
        
        
          c
        
        
          =8MPa
        
        
          T= -30
        
        
          0
        
        
          C
        
        
          (a)
        
        
          0.72
        
        
          0.76
        
        
          0.80
        
        
          0.84
        
        
          2.2
        
        
          2.3
        
        
          2.4
        
        
          2.5
        
        
          2.6
        
        
          2.7
        
        
          5
        
        
          0
        
        
          C
        
        
          -10
        
        
          0
        
        
          C
        
        
          Elastic modulus
        
        
          (
        
        
          10
        
        
          8
        
        
          Pa
        
        
          )
        
        
          Density
        
        
          (
        
        
          g/cm
        
        
          3
        
        
          )
        
        
          p
        
        
          0
        
        
          = 8MPa
        
        
          T=-30
        
        
          0
        
        
          C
        
        
          (b)
        
        
          Figure 4. Elastic modulus of pure MH measured (a) at a given
        
        
          temperature but varied confining pressure; and (b) at a given confining
        
        
          pressure but varied temperatures (data from Hyodo et al. 2005)
        
        
          2.4
        
        
          Bond tension/compression strength
        
        
          The bond tension and compression strength (i.e.,
        
        
          R
        
        
          t
        
        
          and
        
        
          R
        
        
          c
        
        
          in
        
        
          Eqs. (4) and (5)) can be computed from the tension/compression
        
        
          strength,
        
        
          q
        
        
          max
        
        
          ,
        
        
          t
        
        
          and
        
        
          q
        
        
          max,c
        
        
          , of pure MH specimen subjected to a
        
        
          given confining pressure
        
        
          p
        
        
          c
        
        
          , i.e.,
        
        
          max,
        
        
          t
        
        
          R Rq
        
        
          
        
        
          
        
        
          t
        
        
          (9a)
        
        
          max,
        
        
          c
        
        
          R Rq
        
        
          
        
        
          
        
        
          c
        
        
          (9b)
        
        
          As partially shown in Fig. 5, the peak deviator stress
        
        
          q
        
        
          max,c
        
        
          obtained from the compression triaxial test on pure MH
        
        
          specimens is a function of
        
        
          T
        
        
          ,
        
        
          p
        
        
          c
        
        
          and
        
        
          
        
        
          (Hyodo et al. 2005). The
        
        
          regression analysis of these data yields another empirical
        
        
          formula:
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          max,
        
        
          0
        
        
          0.81
        
        
          2.08
        
        
          184.16
        
        
          134.65
        
        
          c a
        
        
          c a
        
        
          w
        
        
          q p
        
        
          p p
        
        
          T T
        
        
           
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          (10a)
        
        
          Eq. (9) is assumed to hold for tension triaxial test as well,
        
        
          leading to the following:
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          max,
        
        
          0
        
        
          0.81 2.08
        
        
          184.16
        
        
          134.65
        
        
          t
        
        
          a
        
        
          w
        
        
          q p
        
        
          p
        
        
          T T
        
        
           
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          (10b)
        
        
          where
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          
        
        
          0
        
        
          0.55
        
        
          1.15
        
        
          100.09
        
        
          74.39
        
        
          c a
        
        
          w
        
        
          p
        
        
          p p
        
        
          T T
        
        
           
        
        
           
        
        
          
        
        
          
        
        
          
        
        
          (11)
        
        
          2.5
        
        
          Fitting parameters
        
        
          As already demonstrated in Fig. 2, the shape of the bond
        
        
          strength envelope is controlled by the cementation materials,
        
        
          resulting in different values of fitting parameters used in Eqs. (4)
        
        
          and (5). Direct calibration of those parameters are rather
        
        
          difficult for hydrate bonds. We assume that bond strengths are
        
        
          dominated by the strength properties of cementation materials.
        
        
          Fig. 6(a) shows the yielding curves of different materials. The
        
        
          yielding curve is left skewed for cement-based materials and
        
        
          right skewed for epoxy. Unfortunately, we are not able to
        
        
          present the yielding curve for MH due to insufficiency of test
        
        
          data available. As an ice-like material, MH was found similar to
        
        
          ice in some physical properties (Solan et al. 1998; Dvorkin et al.
        
        
          2000) and mechanical properties (Nabeshima et al. 2003; Choi
        
        
          et al. 2009). Instead of MH, the yielding curve of ice is plotted
        
        
          in Fig. 6(b) for comparison, which displays left skewed. We
        
        
          concluded that the MH bonds produce a bond strength envelope
        
        
          similar to cement bonds. The fitting parameters calibrated using
        
        
          cement-bonded grains are used for MH-bonded grains. Eq. (5)
        
        
          is re-written as:
        
        
          0.38
        
        
          1.16 0.498 (
        
        
          ) [(
        
        
          ) / (
        
        
          )]
        
        
          sb
        
        
          n
        
        
          t
        
        
          c
        
        
          n
        
        
          n
        
        
          t
        
        
          R
        
        
          F R R F F
        
        
           
        
        
          
        
        
           
        
        
          
        
        
          
        
        
          0.38
        
        
          R
        
        
          R
        
        
          (12a)
        
        
          1.13 0.96 (
        
        
          ) [(
        
        
          ) / (
        
        
          )]
        
        
          rb
        
        
          n
        
        
          t
        
        
          c
        
        
          n
        
        
          n
        
        
          t
        
        
          R
        
        
          F R R F F
        
        
           
        
        
          
        
        
           
        
        
          
        
        
          
        
        
          (12b)
        
        
          Suppose a MHBS sample collected at 800 m below the sea
        
        
          level (giving a pore water pressure of 8 MPa applied on MH
        
        
          bonds in the sample) at 5C. The gradation curve of the soil
        
        
          grains is assumed to be Fig. 3(b) and the initial void ratio of the
        
        
          sample is 0.21. For a given
        
        
          S
        
        
          Hb
        
        
          , the parameter
        
        
          
        
        
          is determined
        
        
          from the chart presented in Fig. 3(a).
        
        
          R
        
        
          t
        
        
          and
        
        
          R
        
        
          c
        
        
          computed from
        
        
          Eqs. (9) to (11) are then substituted into Eq. (12) to obtain the
        
        
          bond strength envelope. Fig. 7 illustrates a series of strength
        
        
          envelopes at different levels of hydrate saturation. As expected,
        
        
          the envelope expands omothetically with
        
        
          S
        
        
          Hb
        
        
          .
        
        
          0 2
        
        
          4
        
        
          6 8 10
        
        
          0
        
        
          5
        
        
          10
        
        
          15
        
        
          20
        
        
          25
        
        
          q
        
        
          max
        
        
          (MPa)
        
        
          Comfining pressure
        
        
          p
        
        
          0
        
        
          (MPa)
        
        
          T
        
        
          = -30
        
        
          ℃
        
        
          
        
        
          = 0.8g/cm
        
        
          3
        
        
          (a)
        
        
          10 0 -10 -20 -30 -40
        
        
          0
        
        
          5
        
        
          10
        
        
          15
        
        
          20
        
        
          25
        
        
          High purity
        
        
          Low purity
        
        
          q
        
        
          max
        
        
          (MPa)
        
        
          Temperature
        
        
          (
        
        
          ℃
        
        
          )
        
        
          p
        
        
          0
        
        
          = 8MPa
        
        
          
        
        
          = 0.8g/cm
        
        
          3
        
        
          (b)
        
        
          Figure 5. The maximum deviator stress of pure MH measured (a) at a
        
        
          given temperature but varied confining pressure; and (b) at a given
        
        
          confining pressure but varied temperatures (data from Hyodo et al. 2005)
        
        
          -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5
        
        
          0.0
        
        
          0.5
        
        
          1.0
        
        
          1.5
        
        
          2.0
        
        
          2.5
        
        
          3.0
        
        
          Cement-based
        
        
          Epoxy resin
        
        
          Hussein & Marzouk 2000
        
        
          Kupfer et al., 1967
        
        
          Ellyin et al., 2005
        
        
          
        
        
          3
        
        
          /
        
        
          
        
        
          3max
        
        
          (
        
        
          
        
        
          1
        
        
          -
        
        
          
        
        
          3
        
        
          )/
        
        
          
        
        
          3max
        
        
          (a)
        
        
          -0.3 0.0 0.3 0.6 0.9 1.2
        
        
          0.00
        
        
          0.05
        
        
          0.10
        
        
          0.15
        
        
          Nadreau & Michel 1986
        
        
          
        
        
          3
        
        
          /
        
        
          
        
        
          3max
        
        
          (
        
        
          
        
        
          1
        
        
          -
        
        
          
        
        
          3
        
        
          )/
        
        
          
        
        
          3max
        
        
          ice
        
        
          (b)
        
        
          Figure 6. Yielding curves obtained from experiments for: (a) cement-
        
        
          based materials and epoxy resin; and (2) ice
        
        
          -20 -10 0 10 20 30 40
        
        
          0
        
        
          5
        
        
          10
        
        
          15
        
        
          20
        
        
          25
        
        
          15%
        
        
          24%
        
        
          S
        
        
          Hb
        
        
          =41%
        
        
          R
        
        
          sb
        
        
          (
        
        
          kN)
        
        
          Normal force
        
        
          F
        
        
          n
        
        
          (kN)
        
        
          -20 -10 0 10 20 30 40
        
        
          0
        
        
          10
        
        
          20
        
        
          30
        
        
          40
        
        
          15%
        
        
          24%
        
        
          S
        
        
          Hb
        
        
          =41%
        
        
          R
        
        
          rb
        
        
          (
        
        
          N
        
        
          
            ·
          
        
        
          m)
        
        
          Normal force
        
        
          F
        
        
          (a)
        
        
          (b)
        
        
          n
        
        
          (kN)
        
        
          Figure 7. Bond strength envelopes at different hydrate saturation: (a)
        
        
          relationship between
        
        
          R
        
        
          sb
        
        
          and
        
        
          F
        
        
          n
        
        
          ; and (b) relationship between
        
        
          R
        
        
          rb
        
        
          and
        
        
          F
        
        
          n
        
        
          3 DEM SIMULATION OF BIAXIAL TESTS ON MHBS
        
        
          The proposed model for MHBS was implemented into the
        
        
          commercial code PFC2D for simulating the biaxial compression
        
        
          test on a MHBS specimen. For inter-particle contacts with
        
        
          broken bonds or without bonds,
        
        
          
        
        
          = 0.5,
        
        
          K’
        
        
          n
        
        
          = 3.0×10
        
        
          8
        
        
          N/m,
        
        
          K’
        
        
          s
        
        
          = 2.0×10
        
        
          8
        
        
          N/m. The model parameters for other contacts with
        
        
          intact MH bonds were determined as explained in Section 2.
        
        
          A 40×80 cm virtual specimen was first generated using the
        
        
          multi-layer with under-compaction method (Jiang et al. 2003).
        
        
          The resulted specimen with an initial planar void ratio of 0.21
        
        
          was composed of 6000 disks with radii ranging from 6 to 9 mm,
        
        
          forming a gradation curve shown in Fig. 3(b). The specimen
        
        
          was consolidated by applying an isotropic pressure of 1 MPa
        
        
          until force balance was maintained. The gravity was ignored in
        
        
          the whole simulation. Bonds were then assigned to the contacts
        
        
          of particles. As the force system was balanced, the top wall
        
        
          moved downward at a speed of 5% per minute to simulate the
        
        
          displacement-controlled shearing process. Frictionless rigid
        
        
          walls were used in the simulation in stead of flexible walls to
        
        
          reduce the computational time. The boundary type selected will
        
        
          not affect the stress-strain response, while it however will
        
        
          change the formation of shear bands.